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You can't use casted parts everywhere because if you wanted to use them on the body sides, it would be fine until you start crashing the car. The problem is simple. The casted parts, maybe they are strong, but they are brittle. They don't deform, they don't absorb energy. Once you apply higher force, those parts basically break and the person inside the vehicle is killed. It's done.
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It depends on the crystalline structure of the material. If it's iron with a lower carbon content, it will bend nicely. However, if you introduce a higher amount of carbon, it can become brittle. In the car industry, there's a focus on CO2 emissions, and you want a nice balance between weight and strength. Aluminum is advantageous because it fills the form nicely, is light, and has high strength.
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That's a good question. To be honest, I don't know. I don't think there's currently a material or aluminum chemistry that makes aluminum not brittle. It can withstand some forces, but once you surpass a certain threshold, it will crack.
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